New technique welcomes calcium-41 to radiometric dating

Context

  • Scientists have suggested using Calcium-41 for Radiometric Dating as an alternative to Carbon-14 for determining the age of fossilized bones and rocks.

Background

  • Since its invention in 1947, carbon dating has revolutionised many fields of science by allowing scientists to estimate the age of an organic material based on how much carbon-14 it contains.
  • However, carbon-14 has a half-life of 5,700 years, so the technique cannot determine the age of objects older than around 50,000 years.
  • In 1979, scientists suggested using calcium-41, with a half-life of 99,400 years..

Calcium-14

  • It is produced when cosmic rays from space smash into calcium atoms in the soil, and is found in the earth’s crust, opening the door to dating fossilised bones and rock.
  • When an organic entity is alive, its body keeps absorbing and losing carbon-14 atoms. When it dies, this process stops and the extant carbon-14 starts to decay away.
  • Using the difference between the relative abundance of these atoms in the body and the number that should have been there, researchers can estimate when the entity died.

Atom-Trap Trace Analysis (ATTA) technique

  • A significant early issue with carbon dating was to detect carbon-14 atoms, which occur once in around 1,012carbon atoms. Calcium-41 is rarer, occurring once in around 1,015calcium atoms.
  • In the new study, researchers have pitched a technique called atom-trap trace analysis (ATTA) as a solution.
  • ATTA is sensitive enough to spot these atoms; specific enough to not confuse them for other similar atoms and fits on a tabletop.
  • A sample is vaporised in an oven. The atoms in the vapour are laser-cooled and loaded into a cage made of light and magnetic fields.
  • In an atom, an electron in one orbital can transition to the next if it’s given a specific amount of energy; then it jumps back by releasing that energy.
  • In ATTA, a laser’s frequency is tuned such that it imparts the same energy as required for an electron transition in calcium-41. The electrons absorb and release this energy, revealing the presence of their atoms.
  • ATTA also avoids potassium-41 atoms, which are similar to calcium-41 atoms but lack the same electron transition.

Application of ATTA and Calcium-41

  • Opens the possibility of extension to other metal isotopes
  • To study how long rocks has been covered by ice
  • Open avenues for exploring Earth-science applications